Q. Which of the following species does not exert a resonance effect ?

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A

$C _{6} H _{5} NH _{3}{ }^{+}$

B

$C _{6} H _{5} NH _{2}$

C

$C _{6} H _{5} Cl$

D

$C _{6} H _{5} OH$

Solution:

In $C _{6} H _{5} NH _{3}{ }^{+}$, there is no lone pair of electrons on nitrogen atom. Hence it can not show resonance.

Questions from KCET 2022

1. Clathatiates or Cage compounds formed by

2. The eleetron affinity. of halugens follow the order

3. Conductivity of a solution is directly proportional to

4. Which of the following is a Lewis acid ?

5. For the reaction $A+B \rightarrow C+D$, it is found that doubling the concentration of $A$ increases rate 4 times and doubling the concentration of B doubles the reaction rate. What is the overall order of the reaction ?

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1. If for a certain reaction $\Delta_{r}H$ is $30\, kJ\, mol^{-1}$ at $450 \,K$, the value of $\Delta_{r}S$ (in $JK^{-1}\, mol^{-1})$ for which the same reaction will be spontaneous at the same temperature is

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2. If $8\,g$ of a non-electrolyte solute is dissolved in $114\, g$ of n-octane to reduce its vapour pressure to $80\%$, the molar mass (in $g \,mol^{-1})$ of the solute is [Given that molar mass of n-octane is $114 \,g\, mol^{-1}]$

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3. An organic compound contains $78 \%$ (by wt.) carbon and remaining percentage of hydrogen. The right option for the empirical formula of this compound is: [Atomic wt. of $C$ is $12, H$ is $1$]

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4. At standard conditions, if the change in the enthalpy for the following reaction is $-109 \,kJ\, mol^{-1}$ $H_{2(g)}+Br_{2(g)} \to 2HBr_{(g)}$ Given that bond energy of $H_{2}$ and $Br_{2}$ is $435\,KJ\,mol^{-1}$ and $192\,KJ\,mol^{-1}$ , respectively, what is the bond energy (in $KJ \,mol^{-1})$ of $HBr$ ?

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5. The density of 2 M aqueous solution of NaOH is 1.28 g/cm$^3$. The molality of the solution is
[Given that molecular mass of NaOH = 40 g mol$^{-1}$]

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