Q. The $C-C$ bond distance is the longest in

Solution:

In $C_2 H_ 2$ there is $C \equiv C$. In $C_2 H_4$ and $C_2 H_ 2 Br_2$ there is $C = C$.
In $C _2 H_ 6$ there is $C - C$.
$C-C$ bond distance is longest.