Q. A compound $(X)$ has the molecular formula $C _{7} H _{7} NO$. On treatment with $Br _{2}$ and $KOH ,( X )$ gives an amine $( Y ) ;( Y )$ gives carbylamine test. (Y) upon diazotisation and coupling with phenol gives an azo dye $(Z) .(X)$ is:
Amines
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Solution:
Reaction of $( X )$ with $Br _{2}+ KOH$ suggests that $( X )$ is an amide. Carbylamine test and coupling reaction of $(Y)$ suggest that $(Y)$ is $1^{\circ}$ aromatic amine.

Questions from Amines
1. Which one of the following is not a primary amine?
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3. An organic compound contains $78 \%$ (by wt.) carbon and remaining percentage of hydrogen. The right option for the empirical formula of this compound is: [Atomic wt. of $C$ is $12, H$ is $1$]
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5. The density of 2 M aqueous solution of NaOH is 1.28 g/cm$^3$. The molality of the solution is
[Given that molecular mass of NaOH = 40 g mol$^{-1}$]
NEET 2019
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