Q. Which monomer would polymerise in isotactic, syndiotactic, and atactic forms?

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A

$CH _{2}= CCl _{2}$

B

$CH _{3}- CH = CH _{2}$

C

$Ph - CH = CH _{2}$

D

All

Solution:

Correct answer is (b) $CH _{3}- CH = CH _{2}$Correct answer is (c) $Ph - CH = CH _{2}$

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1. What is the $ IUPAC $ nomenclature of isoprene monomer present in natural rubber ?

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2. Dacron is continuous filament yarn used in curtains, dress fabrics and pressure fire hoses. The reaction for preparing dacron is by the combination of which of the following ?

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3. Major product of the following reaction is :

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4. Which of the following is a characteristic of Low-Density Polyethylene $ (LDPE) $ ?

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5. Choose the correct option(s) from the following

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1. If for a certain reaction $\Delta_{r}H$ is $30\, kJ\, mol^{-1}$ at $450 \,K$, the value of $\Delta_{r}S$ (in $JK^{-1}\, mol^{-1})$ for which the same reaction will be spontaneous at the same temperature is

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2. If $8\,g$ of a non-electrolyte solute is dissolved in $114\, g$ of n-octane to reduce its vapour pressure to $80\%$, the molar mass (in $g \,mol^{-1})$ of the solute is [Given that molar mass of n-octane is $114 \,g\, mol^{-1}]$

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3. An organic compound contains $78 \%$ (by wt.) carbon and remaining percentage of hydrogen. The right option for the empirical formula of this compound is: [Atomic wt. of $C$ is $12, H$ is $1$]

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4. At standard conditions, if the change in the enthalpy for the following reaction is $-109 \,kJ\, mol^{-1}$ $H_{2(g)}+Br_{2(g)} \to 2HBr_{(g)}$ Given that bond energy of $H_{2}$ and $Br_{2}$ is $435\,KJ\,mol^{-1}$ and $192\,KJ\,mol^{-1}$ , respectively, what is the bond energy (in $KJ \,mol^{-1})$ of $HBr$ ?

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5. The density of 2 M aqueous solution of NaOH is 1.28 g/cm$^3$. The molality of the solution is
[Given that molecular mass of NaOH = 40 g mol$^{-1}$]

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