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  4. A tetra-atomic molecule X on reaction with nitrogen oxide (Oxidation State = 1) produces two substances Y and Z. Y is a dehydrating agent while compound Z is a diatomic gas which shows almost inert gas behavior. The substances X, Y and Z are

Q. A tetra-atomic molecule X on reaction with nitrogen oxide (Oxidation State = 1) produces two substances Y and Z. Y is a dehydrating agent while compound Z is a diatomic gas which shows almost inert gas behavior. The substances X, Y and Z are

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Solution:

When P4 is treated with N2O (O.S = 1) it produces P4O10 and N2 (diatomic molecule).
P4O10 used as dehydrating agent
$\left(\text{P}\right)_{4} & + & 10\left(\text{N}\right)_{2}\text{O} & \rightarrow & \left(\text{P}\right)_{4}\left(\text{O}\right)_{1 0} & + & 10\left(\text{N}\right)_{2} \\ \left(\text{X}\right) & & & & \left(\text{Y}\right) & & \left(\text{Z}\right)$

Questions from NTA Abhyas 2022

1. An alkene $\left(\right.A\left.\right)$ on ozonolysis gives a mixture of two carbonyl compounds. Mixture on Clemmensen reduction gives just one alkane $\left(\right.B\left.\right)$ . $\left(\right.B\left.\right)$ is the lowest alkane which in pure form can not be prepared by standard Wurtz method. $\left(\right.A\left.\right)$ is

2. A cation is in the centre touches three anions. Assume that the anions also touch each other. The limiting radius ratio, $r^{+}/r^{-}$ is

3. Blue colour of alkali and alkaline earth metals in liquid $NH_{3}$ is due to

4. Which of the following oxides is strongly basic?

5. In a $10litre$ box $2.5mole$ hydroiodic acid is taken. After equilibrium $2HI\rightleftharpoonsH_{2}+I_{2}$ the concentration of $HI$ is found to be $0.1 \, \text{mol} \, \text{L}^{- 1}$ . The concentration of $\left[H_{2}\right]$ at equilibrium in $molL^{- 1}$ , is

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1. If for a certain reaction $\Delta_{r}H$ is $30\, kJ\, mol^{-1}$ at $450 \,K$, the value of $\Delta_{r}S$ (in $JK^{-1}\, mol^{-1})$ for which the same reaction will be spontaneous at the same temperature is

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2. If $8\,g$ of a non-electrolyte solute is dissolved in $114\, g$ of n-octane to reduce its vapour pressure to $80\%$, the molar mass (in $g \,mol^{-1})$ of the solute is [Given that molar mass of n-octane is $114 \,g\, mol^{-1}]$

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3. An organic compound contains $78 \%$ (by wt.) carbon and remaining percentage of hydrogen. The right option for the empirical formula of this compound is: [Atomic wt. of $C$ is $12, H$ is $1$]

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4. At standard conditions, if the change in the enthalpy for the following reaction is $-109 \,kJ\, mol^{-1}$ $H_{2(g)}+Br_{2(g)} \to 2HBr_{(g)}$ Given that bond energy of $H_{2}$ and $Br_{2}$ is $435\,KJ\,mol^{-1}$ and $192\,KJ\,mol^{-1}$ , respectively, what is the bond energy (in $KJ \,mol^{-1})$ of $HBr$ ?

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5. The density of 2 M aqueous solution of NaOH is 1.28 g/cm$^3$. The molality of the solution is
[Given that molecular mass of NaOH = 40 g mol$^{-1}$]

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