Q. If (dl) or ( $\pm$ ) 2-methyl butanoic acid were esterified by reaction with (dl) or ( $\pm$ ) 2-butanol, how many optically active compounds would be present in the final equilibrium reaction mixture?

Alcohols Phenols and Ethers Report Error

Solution:

$(dl) 2$-methyl butanoic acid and $(dl) 2$-butanol

Ester consists of two stereocentres. Chiral center during whole reaction are not effected, that's why all esters are optical active.

Questions from Alcohols Phenols and Ethers

1. Order of acidic nature of the following compounds is

AIIMS 2019

2. An unknown alcohol is treated with the Lucas reagent to determine whether the alcohol is primary, secondary or tertiary. Which alcohol reacts fastest and by what mechanism?

UP CPMT 2015

3. $C_6H_5OH \xrightarrow[(ii)\, dil. HCl]{(i)\,CCl_4, NaOH} X \xrightarrow[\text{heat}]{Zn\,\text{dust}} Y \xrightarrow[(ii)\,\text{soda lime}]{(i)\,Na}Z$. What is $Z$ ?

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4. Reaction of propene with diborane followed alkaline hydrolysis in the presence of hydrogen peroxide gives

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5. Assertion: Phenol reacts with $CH_3I$ in presence of NaOH to form methoxybenzene.
Reason : Phenoxide is better nucleophile than phenol.

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Chemistry Most Viewed Questions

1. If for a certain reaction $\Delta_{r}H$ is $30\, kJ\, mol^{-1}$ at $450 \,K$, the value of $\Delta_{r}S$ (in $JK^{-1}\, mol^{-1})$ for which the same reaction will be spontaneous at the same temperature is

NEET 2020 Thermodynamics

2. If $8\,g$ of a non-electrolyte solute is dissolved in $114\, g$ of n-octane to reduce its vapour pressure to $80\%$, the molar mass (in $g \,mol^{-1})$ of the solute is [Given that molar mass of n-octane is $114 \,g\, mol^{-1}]$

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3. At standard conditions, if the change in the enthalpy for the following reaction is $-109 \,kJ\, mol^{-1}$ $H_{2(g)}+Br_{2(g)} \to 2HBr_{(g)}$ Given that bond energy of $H_{2}$ and $Br_{2}$ is $435\,KJ\,mol^{-1}$ and $192\,KJ\,mol^{-1}$ , respectively, what is the bond energy (in $KJ \,mol^{-1})$ of $HBr$ ?

NEET 2020 Thermodynamics

4. An organic compound contains $78 \%$ (by wt.) carbon and remaining percentage of hydrogen. The right option for the empirical formula of this compound is: [Atomic wt. of $C$ is $12, H$ is $1$]

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5. The density of 2 M aqueous solution of NaOH is 1.28 g/cm$^3$. The molality of the solution is
[Given that molecular mass of NaOH = 40 g mol$^{-1}$]

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6. Given below are half cell reactions:
$ MnO _{4}^{-}+8 H ^{+}+5 e ^{-} \rightarrow Mn ^{2+}+4 H _{2} O $
$ E _{ Mn ^{2+} / MnO _{4}^{-}}^{\circ}=-1.510\, V$
$\frac{1}{2} O _{2}+2 H ^{+}+2 e ^{-} \rightarrow H _{2} O ,$
$ E _{ O _{2} / H _{2} O }^{\circ}=+1.223 \,V$
Will the permanganate ion, $MnO _{4}^{-}$liberate $O _{2}$ from water in the presence of an acid ?

NEET 2022 The d-and f-Block Elements

7. In water saturated air the mole fraction of water vapour is $0.02$. If the total pressure of the saturated air is $1.2\, atm$, the partial pressure of dry air is :

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8. Following limiting molar conductivities are given as
$\lambda^{o}_{m}\left(H_{2}SO_{4}\right) \,= \,x S\, cm^{2} mol^{-1}$
$\lambda^{o}_{m}\left(K_{2}SO_{4}\right) = y S\,cm^{2} mol^{-1}$
$\lambda^{o}_{m}\left(CH_{3}COOK\right) =z S\, cm^{2} mol^{-1} $
$\lambda^{o}_{m}\left(in \,S \,cm^{2} mol^{-1}\right)$ for $CH_3COOH$ will be-

NEET 2019 Electrochemistry

9. One atom of an element weighs $ 1.8\times 10^{-22}g$ . Its atomic mass is

Manipal 2009 Some Basic Concepts of Chemistry

10. In the following reaction,
$H_3C-C\equiv CH\xrightarrow [{873\, K}] {\text{red hot iron tube}}$A,
the number of sigma(s) bonds present in the product A is :-

NEET 2019 Hydrocarbons