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- Identify how many compounds are more basic than aniline. <img class=img-fluid question-image alt=image src=https://cdn.tardigrade.in/img/question/chemistry/d7ec100a54df0b28b2d53a96b6a7f06b-.png /> <img class=img-fluid question-image alt=image src=https://cdn.tardigrade.in/img/question/chemistry/f473e4686507574acfb691806e688094-.png />
Q.
Identify how many compounds are more basic than aniline.
Amines
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Solution:
Five compounds $(2,3,5,6$, and 7) are more basic than aniline.
(2) $\Rightarrow$ No delocalisation of lone pair of electrons on $N$ atom
(3) $\Rightarrow\left(- OCH _{3}\right)$ is EDG $(+ R >- I )$.
(5) $\Rightarrow$ Two $N$-atom with lone pairs
(6) $\Rightarrow$ Three $N$-atoms with lone pairs
(7) $\Rightarrow$ No delocalisation of lone pair of electrons on $N$-atom.
Moreover $1^{\circ}$ aliphatic amines are more basic than aniline
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