Q.

Column I Reactions Column II Mechanism

a
p Vinylic radical

b
q Radical anion

c
r trans-Vinylic anion

d
s Concerted mechanism

Alcohols Phenols and Ethers Report Error

A

B

C

D

Solution:

a. It is pinacol formation which proceeds by radical anion.
b. It is Birch reduction which proceeds by the formation

c. It is an example of Claisen rearrangement reaction and proceeds by concerted mechanism.
d. It is an example of Diels-Alder reaction and proceeds by concerted mechanism.

Questions from Alcohols Phenols and Ethers

1. The correct IUPAC name of the organic compound

KEAM 2014

2. Order of acidic nature of the following compounds is

AIIMS 2019

3. Assertion: Phenol reacts with in presence of NaOH to form methoxybenzene.
Reason : Phenoxide is better nucleophile than phenol.

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4. Assertion : Hydroquinone is more acidic than resorcinol.
Reason : group shows .

AIIMS 2019

5. Dehydration of which one of the following alcohols produces an alkene exhibiting isomerism?

KEAM 2015

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5. The density of 2 M aqueous solution of NaOH is 1.28 g/cm. The molality of the solution is
[Given that molecular mass of NaOH = 40 g mol]

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