High density polythene (HDP) or high density polyethylene (HDPE) is prepared by coordination polymerization of ethene at 60∘−160∘C and 6-7 atm. pressure in the presence of Zeigler-Natta catalyst (triethylaluminium and titanium trichloride or tetrachloride).
nCH2=CH2333−343K6−7atmZeigler Natta catalystHigh density polythene[CH2−CH2]n