Depression in freezing point ∝ no. of particles in the solution No. of particlesNH4Cl2BaSO42K2Cr2O73Al2(SO4)35
The depression in freezing points (ΔTf) will be in the order; NH4Cl=BaSO4<K2Cr2O7<Al2(SO4)3
Thus, Al2(SO4)3 will have maximum depression in freezing point i.e., its actual freezing point will be minimum.