Q.
Which one of the following does not form sodium bisulphite addition product with sodium bisulphite solution?
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J & K CETJ & K CET 2009Aldehydes Ketones and Carboxylic Acids
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Solution:
Acetophenone (C6H5COCH3) does not give addition product with sodium bisulphite (NaHSO3) solution. This is because, two bulkier groups are attached with the carbonyl carbon. These groups decrease the reactivity of carbonyl carbon.