Acetaldehyde give both Tollen's reagent and Fehling's solution test Acetaldehyde reduce Tollen's reagent to give silver mirror. CH3−CH=O+2[Ag(NH3)2]++3OH− →CH3COOH+silver mirror2Ag+4NH3+H2O
and acetaldehyde reduce fehling solution to red cuprous oxide. CH3CHO+(Fehling solution)2Cu+2+5OH−⟶CH3COOH +red p.pt (cuprous oxide)Cu2O↓+3H2O