Coal gas with H2(49%),CH4(32%) and CO(8%) has the highest calorific value. Water gas with CO(48%) and H2(51%) has lesser calorific value than coal gas. Producer gas with CO(35%) and N2(65%) has a still lesser calorific value. CO2 has no calorific value. Thus calorific values decrease in the order.
coal gas > water gas > producer gas