OH group is an activating group and it increase electron density on o- and p - position in benzene ring. When phenol reacts with cone. HNO3 in the presence of cone. H2SO4 , then nitration (electrophilic substitution) takes place and 2,4,6-trinitrophenol is obtained.
2,4,6-trinitrophenol is also called picric acid. It is an explosive.