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Question
Chemistry
Which branched chain isomer of the hydrocarbon with molecular mass 72u gives only one isomer of mono substituted alkyl halide?
Q. Which branched chain isomer of the hydrocarbon with molecular mass 72u gives only one isomer of mono substituted alkyl halide?
2516
197
Haloalkanes and Haloarenes
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A
Tertiary butyl chloride
38%
B
Neopentane
35%
C
Isohexane
19%
D
Neohexane
8%
Solution:
Molar mass
=
72
=
C
n
H
2
n
+
2
=
12
n
+
(
2
n
+
2
)
n
=
5
Thus, hydrocarbon is
C
5
H
12
. Since, it gives only single
C
5
H
11
C
1
. This suggests that
C
5
H
12
is symmetrical.
Hence, it is containing all 12 equivalent H-atoms.