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Q. Which branched chain isomer of the hydrocarbon with molecular mass 72u gives only one isomer of mono substituted alkyl halide?

Haloalkanes and Haloarenes

Solution:

Molar mass $= 72 = C_{n}H_{2n + 2} = 12n + (2n + 2) n = 5$
Thus, hydrocarbon is $C_{5}H_{12}$
. Since, it gives only single $C_{5}H_{11}C1$. This suggests that $C_{5}H_{12}$ is symmetrical.
Hence, it is containing all 12 equivalent H-atoms.
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