Q.
Which bond angle θ would result in the maximum dipole moment for the triatomic molecule XY2 as shown below?
1978
216
Chemical Bonding and Molecular Structure
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Solution:
The dipole moment of two dipoles inclined at an angle θ is given by the equation,
μ=X2+Y2+2XYcosθ
cos90∘=0. As the angle increases from 90∘ to 180∘, the value of cosθ becomes more and more − ve and hence resultant decreases. Thus, dipole moment is maximum when θ=90∘.