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Chemistry
When PCl5 reacts with sulphuric acid, sulphuryl chloride (SO2Cl2) is formed as the final product. This shows that sulphuric acid:
Q. When
PC
l
5
reacts with sulphuric acid, sulphuryl chloride
(
S
O
2
C
l
2
)
is formed as the final product. This shows that sulphuric acid:
1560
220
Manipal
Manipal 2003
The p-Block Elements - Part2
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A
has two hydroxyl groups in its structure
B
is a derivative of sulphur dioxide
C
is a dibasic acid
D
has greater affinity for water
Solution:
PC
l
5
attacks - OH group and replace it by
−
Cl
group. Hence, reaction of
PC
l
5
with
H
2
S
O
4
shows the presence of 2
−
O
H
groups in
H
2
S
O
4