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Question
Chemistry
The rate constant is given by the equation k=PZe-E/RT, which factor should register a decrease for the reaction to proceed more rapidly?
Q. The rate constant is given by the equation
k
=
PZ
e
−
E
/
RT
,
which factor should register a decrease for the reaction to proceed more rapidly?
2105
212
Chhattisgarh PMT
Chhattisgarh PMT 2005
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A
T
B
Z
C
E
D
P
Solution:
From Arrhenius equation
k
=
A
Z
e
−
E
a
/
RT
where,
A
is
=
frequency factor
E
a
=
energy of activation
e
−
E
a
/
RT
=
Boltzmann factor
A
decrease in activation energy
(
E
a
)
will
increase rate constant
(
k
)
and rate of reaction increase.