Q. The orbital diagram in which Aufbau principle is violated is

 5801  200 IIT JEEIIT JEE 1988Structure of Atom Report Error

Solution:

In option , Aufbau principle is violated. According to this rule, the orbital with lower value of , i.e., will be filled first completely.
In option "Hund's rule of maximum multiplicity" is violated. According to this rule, the pairing of electrons in orbitals of a subshell does not take place untill all the orbitals of a subshell are singly occupied.