Q.
The major product of the reaction between CH3CH2ONa and (CH3)3CCl in ethanol is
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KVPYKVPY 2015Organic Chemistry – Some Basic Principles and Techniques
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Solution:
The major product of the reaction between CH3,CH2ONa and (CH3)3CCl in ethanol is 2-methyl propene.
As (CH3)3CC1 is tertiary halide and CH3CH2O−Na+ is a strong base, so elimination is favoured over substitution
reaction and the resultant product is an alkene. This type of elimination is known as (β-elimination, where hydrogen is eliminated from β-carbon and the halogen is lost from α-carbon atom.