Unsaturated compounds like ethylene and acetylene decolourise Br2 water. Acetylene gives precipitate with ammoniacal AgNO3 but with ammoniacal AgNO3 ethylene do not give any reaction. CH∣∣∣CHAg(NH3)2NO3C.Ag∣∣∣CHAg(NH3)2NO3(whiteppt)DisilveracetylideC.Ag∣∣∣C.AgC2H4Ag(NH3)2NO3 No reaction