Average speed (vav) of gas molecules is inversely proportional to the square root of the absolute temperature (T) of the gas vav=πM8RT
where R is gas constant and M the molecular weight.
Given, v1=v,M1=64,v2=4v ∴v2v1=M1M2 4vv=64M2 ⇒M2=1664=4
Hence, the gas is helium (molecular mass 4).