Average speed $ (v_{av}) $ of gas molecules is inversely proportional to the square root of the absolute temperature (T) of the gas
$ v_{av} = \sqrt{\frac{8RT}{\pi M}} $
where R is gas constant and M the molecular weight.
Given, $ \, \, \, v_1 = v, M_1 = 64, v_2 = 4v $
$ \therefore \frac{v_1}{v_2} = \sqrt{\frac{M_2}{M_1}} $
$ \frac{v}{4v} = \sqrt{\frac{M_2}{64}} $
$ \Rightarrow M_2 = \frac{64}{16} = 4 $
Hence, the gas is helium (molecular mass 4).