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Question
Chemistry
The co-ordination number and the oxidation state of the element 'M' in the complex [ M(en)2(C2O4)]NO2 where (en) is ethane-1,2-diamine) are, respectively
Q. The co-ordination number and the oxidation state of the element
′
M
′
in the complex
[
M
(
e
n
)
2
(
C
2
O
4
)]
N
O
2
{
where (en) is ethane-1,2-diamine) are, respectively
2819
191
KCET
KCET 2017
Coordination Compounds
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A
6
and
3
40%
B
6
and
2
30%
C
4
and
2
20%
D
4
and
3
10%
Solution:
For the given coordinate compound.
[
M
(
e
n
)
2
(
C
2
O
4
)]
N
O
2
(i)
∵
All the (3) ligands are bi dented thus its coordinate number
=
6
(ii) Oxidation number of
M
will be
x
+
0
+
2
×
(
−
2
)
=
0
−
1
∴
x
(oxidation number of
M
)
=
+
3