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Tardigrade
Question
Chemistry
The chemical reaction, R-CH2COOH xrightarrow[(ii) H2O](i) X2/ textred phosphorus R- underset overset|XCH-COOH is known as
Q. The chemical reaction,
R
−
C
H
2
COO
H
(
i
)
X
2
/
red phosphorus
(
ii
)
H
2
O
R
−
X
∣
C
H
−
COO
H
is known as
2719
224
AMU
AMU 2015
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A
Hunsdiecker reaction
B
Vilsmeier reaction
C
Finkelstein reaction
D
Hell-Volhard-Zelinsky reaction
Solution:
In Hell-Volhard-Zelinsky reaction, a-hydrogen of a carboxylic acid can be replaced by halogen using red phosphorus.
R
−
C
H
2
COO
H
+
X
2
Red P
R
−
X
∣
C
H
−
COO
H
α
-halogenated acids are in fact good starting material for preparing other a-substituted acids.