Q.
Propionic acid with Br2/P yields a dibromo product. Its structure would be
6988
175
AIPMTAIPMT 2009Aldehydes Ketones and Carboxylic Acids
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Solution:
Carbonylic acids reacts with Cl2 or Br2 in presence of red P to give exclusively α-chloro or α-bromo acids.
This reaction is called Hell-Volhard-Zelinsky (HVZ) reduction. This reaction is example of α-H-substitution.