(i) Wurtz reaction: It is method of preparation of alkane by reaction between alkyl halide and sodium. 2RX+2Na Ether R−R+2NaX
(ii) Dehydrogenation: It is method of formation of alkene from alkane.
Hydrogen is removed from alkane during reaction.
(iii) Frankland reaction: alkyl halide RX+Zn+XR→ alkane R+ZnX2
It is method of preparation of alkane from alkyl halide.
(iv) Catalytic hydrogenation: It is method of preparation of alkane from alkene.
Hydrogen is added during this reaction. CH2= propene CH−CH3200−300∘C+H2O CH3− propene CH2−CH3