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Tardigrade
Question
Chemistry
Phenol can be converted to o-hydroxybenzaldehyde by
Q. Phenol can be converted to o-hydroxybenzaldehyde by
9166
138
KEAM
KEAM 2011
Alcohols Phenols and Ethers
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A
Kolbes reaction
9%
B
Reimer-Tiemann reaction
63%
C
Wurtz reaction
17%
D
Cannizaro reaction
3%
E
Sandmeyers reaction
3%
Solution:
Treatment of phenol with chloroform in presence of aqueous
N
a
O
H
or
K
O
H
at
70
∘
C
followed by hydrolysis gives o-hydroxybenzaldehyde (salicylaldehyde) as the major product. This reaction is called Reimer-Tiemann reaction.