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Tardigrade
Question
Chemistry
One compound reacts with chloroform in presence of KOH and produces a bad smell (nause odour) compound. The compound formed is:
Q. One compound reacts with chloroform in presence of
K
O
H
and produces a bad smell (nause odour) compound. The compound formed is:
1520
291
Jharkhand CECE
Jharkhand CECE 2002
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A
C
H
3
C
H
2
N
H
2
B
C
6
H
5
CN
C
C
H
3
C
H
2
NC
D
C
2
H
5
CN
Solution:
This is carbyl amine reaction. In this reaction bad smelling isocyanide is formed by reaction of
1
∘
amine with
C
H
C
l
3
and
K
O
H
. So isocyanide is correct answer.
(
a
)
1
∘
amine
C
H
3
C
H
2
N
H
2
(
b
)
cyanide
C
6
H
5
CN
(
c
)
iso cyanide
C
H
3
C
H
2
NC
(
d
)
cyanide
C
2
H
5
CN