Depression in freezing point is a colligative property, so depends upon the number of particles. Among, potassium chloride (KCl), sodium sulphate (Na2SO4), magnesium sulphate (MgSO4) and magnesium carbonate (MgCO3),Na2SO4 produces maximum number of particles.
Na2SO4⇌3 particles 2Na++SO42−
Thus, it causes maximum depression in freezing point.