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Question
Chemistry
In a one component second order reaction, if the concentration of the reactant is reduced to half, the rate
Q. In a one component second order reaction, if the concentration of the reactant is reduced to half, the rate
1525
192
KVPY
KVPY 2009
Chemical Kinetics
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A
increases two times
B
increases four times
C
decreases to one half
D
decreases to one fourth
Solution:
For second order reaction,
2
A
→
Product
Rate of reaction,
r
=
k
[
A
]
2
.
If the concentration is reduced to half,
i
.
e
.
2
A
∴
r
′
=
k
[
2
A
]
2
r
′
=
4
1
k
[
A
]
2
or
r
′
=
4
1
r