Q. Identify the correct statement regarding a spontaneous process:
(i) Lowering of energy in the process is the only criterion for spontaneity.
(ii) For a spontaneous process in an isolated system, the change in entropy is positive.
(iii) Endothermic processes are never spontaneous.
(iv) Mostly of the exothermic processes are spontaneous.

 744  149 Thermodynamics Report Error

Solution:

Spontaneity of reaction depends on tendency to acquire minimum energy state and maximum randomness. For a spontaneous process in an isolated system, the change in entropy is positive.