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Q. Identify the correct statement regarding a spontaneous process:
(i) Lowering of energy in the process is the only criterion for spontaneity.
(ii) For a spontaneous process in an isolated system, the change in entropy is positive.
(iii) Endothermic processes are never spontaneous.
(iv) Mostly of the exothermic processes are spontaneous.

Thermodynamics

Solution:

Spontaneity of reaction depends on tendency to acquire minimum energy state and maximum randomness. For a spontaneous process in an isolated system, the change in entropy is positive.