Q. Identify the binary mixture(s) that can be separated into individual compounds, by differential extraction, as shown in the given scheme.
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Solution:

(A) Both are soluble in , hence inseparable.
(B) Only benzoic acid is soluble in and , while benzyl alcohol is not. Hence, separable.
(C) Although can enable separation between benzyl alcohol and phenol as only the later is soluble in . However, in , both are insoluble. Hence, inseparable.
(D) -phenyl acetic acid is soluble in and . While benzyl alcohol is not. Hence, separable.