Tardigrade
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Tardigrade
Question
Chemistry
Hoffmann's bromamide reaction is used to
Q. Hoffmann's bromamide reaction is used to
1998
215
J & K CET
J & K CET 2017
Amines
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A
prepare tertiary amine
17%
B
prepare all types of amines
25%
C
step up the series
12%
D
step down the series
45%
Solution:
Hoffmann bromaraide reaction converts acid amides to primary amines :
Acid amide
RCON
H
2
+
B
r
2
+
4
K
O
H
→
1
∘
amine
RN
H
2
+
2
K
B
r
+
K
2
C
O
3
+
2
H
2
O
The
1
∘
amine formed has one carbon atom lesser than that present in acid amide