Diethyl ether can be prepared by the dehydration of ethanol with conc. H2SO4 at 410K. In this method excess of alcohol is heated with conc. H2SO4 at 410K.
In this reaction the temperature must be controlled because at higher temperature (443K), the alcohols get dehydrated to alkenes. CH3CH2OHH2SO4443KCH2=CH2+H2O