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Question
Chemistry
For spontaneous reaction or the reaction at equilibrium which of the following is wrong?
Q. For spontaneous reaction or the reaction at equilibrium which of the following is wrong?
1636
186
Delhi UMET/DPMT
Delhi UMET/DPMT 2006
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A
Δ
H
<
T
Δ
S
reaction is exothermic and
T
Δ
S
is + ve
B
Δ
H
=
−
v
e
,
T
Δ
S
=
0
C
Δ
H
=
T
Δ
S
D
Δ
H
=
−
v
e
,
T
Δ
S
=
−
v
e
Solution:
For a reaction to be spontaneous on the reaction at equilibrium:
Δ
H
=
−
v
e
Δ
S
=
+
v
e
Δ
G
=
Δ
H
−
T
Δ
S
=
−
v
e
So,
Δ
H
<
T
Δ
S
,
reaction is exothermic and
T
Δ
S
is
+
v
e
statement is wrong