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Question
Chemistry
Based on lattice energy and other considerations, which one of the following alkali metal chlorides is expected to have the highest melting point?
Q. Based on lattice energy and other considerations, which one of the following alkali metal chlorides is expected to have the highest melting point?
1696
209
AIIMS
AIIMS 2011
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A
RbCl
B
KCl
C
NaCl
D
LiCl
Solution:
As we go down in the group, ionic character increases hence, melting point of halides should increase but
N
a
Cl
has the highest melting point
(
80
0
∘
C
)
due to its high lattice energy.