Q.
Base strength of
(i) H3CC⊖H2
(ii) H2C=C⊖H
(iii) H−C≡C⊖
is in the order of
4366
203
AIPMTAIPMT 2008Organic Chemistry – Some Basic Principles and Techniques
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Solution:
Weaker the acid, strongest is its conjugate base. Among alkane, alkene and alkyne, alkynes are most acidic and alkanes are least acidic, so the order of base strength is
alkane > alkene > alkyne or CH3C⊖H2>H2C=C⊖H>H−C≡C⊖