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Q. Base strength of
(i) $H _{3} C\overset{{\ominus} }{C} H _{2}$
(ii) $H _{2} C =\overset{\ominus}{ C}H $
(iii) $H - C \equiv C ^{\ominus}$
is in the order of

AIPMTAIPMT 2008Organic Chemistry – Some Basic Principles and Techniques

Solution:

Weaker the acid, strongest is its conjugate base. Among alkane, alkene and alkyne, alkynes are most acidic and alkanes are least acidic, so the order of base strength is
alkane $>$ alkene $>$ alkyne or
$CH _{3} \overset{\ominus}{C}H_{2}> H _{2} C =\overset{\ominus}{ C } H > H - C \equiv \overset{\ominus}{ C }$