Q. Assertion : Alkali metals are obtained by electrolysis of molten salt and not aqueous solution.
Reason : The discharge potential of ions is lower than alkali metal cation hence hydrogen is discharged at cathode instead of metal.

 1791  212 The s-Block Elements Report Error

Solution:

Alkali metals are obtained by electrolysis of molten salt and not aqueous solution because is liberated at cathode instead of alkali metal.