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Q. Assertion : Alkali metals are obtained by electrolysis of molten salt and not aqueous solution.
Reason : The discharge potential of $H^+$ ions is lower than alkali metal cation hence hydrogen is discharged at cathode instead of metal.

The s-Block Elements

Solution:

Alkali metals are obtained by electrolysis of molten salt and not aqueous solution because $H _{2}$ is liberated at cathode instead of alkali metal.