Q. Assertion: parts by mass of carbon in and molecules combine with and parts by mass of oxygen
Reason: A given compound always contains exactly the same proportion of elements by weight

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Solution:

The masses of oxygen (i.e., and ) which combine with a fixed mass of carbon (i.e., ) bear a simple ratio, i.e., or . This explains the law of multiple proportions.
Law of definite proportions states that a given compound always contains exactly the same proportion of element by weight, irrespective of the source.