Q.
An insulator container contains 4 moles of an ideal diatomic gas at temperature T. Heat Q is supplied to this gas, due to which 2 moles of the gas are dissociated into atoms but temperature of the gas remains constant. Then
Q=ΔU=Uf−Ui=
[internal energy of 4 moles of a monoatomic gas + internal energy of 2 moles of a diatomic gas] - [internal energy of 4 moles of a diatomic gas ] =(4×23RT+2×25RT)−(4×25RT)=RT