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Q. An insulator container contains 4 moles of an ideal diatomic gas at temperature $T$. Heat $Q$ is supplied to this gas, due to which 2 moles of the gas are dissociated into atoms but temperature of the gas remains constant. Then

Thermodynamics

Solution:

$Q=\Delta U=U_{f}-U_{i}=$
[internal energy of 4 moles of a monoatomic gas $+$ internal energy of 2 moles of a diatomic gas] - [internal energy of 4 moles of a diatomic gas $]$
$=\left(4 \times \frac{3}{2} R T+2 \times \frac{5}{2} R T\right)-\left(4 \times \frac{5}{2} R T\right)=R T$