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Question
Chemistry
A current strength of 9.65 A is passed through excess fused AICI3 for 5 h How many litres of chlorine will be liberated at STP ? (F = 96500 C)
Q. A current strength of
9.65
A
is passed through excess fused
A
I
C
I
3
for 5 h How many litres of chlorine will be liberated at
STP
?
(
F
=
96500
C
)
3705
215
KEAM
KEAM 2013
Electrochemistry
Report Error
A
2.016
24%
B
1.008
10%
C
11.2
19%
D
20.16
43%
E
10.08
43%
Solution:
From Faraday first law of electrolysis
w
=
z
i
t
z
=
electrons exchanged
×
96500
Atomic mass
C
l
−
⟶
2
1
C
l
2
+
1
e
−
w
=
1
×
96500
35.5
×
9.65
×
5
×
60
×
60
=
63.9
g
∵
At STP,
71
g
C
l
2
has volume
=
22.4
L
∴
At
STP
,
63.9
g
C
l
2
will have volume
=
71
22.4
×
63.9
=
20.16
L