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Question
Chemistry
A conductivity cell has been calibrated with a 0.01 M 1: 1 electrolyte solution (specific conductance, k=1.25 × 10-3 S cm-1) in the cell and the measured resistance was 800 ohms at 25°C. The constant will be
Q. A conductivity cell has been calibrated with a
0.01
M
1
:
1
electrolyte solution (specific conductance,
k
=
1.25
×
1
0
−
3
S
c
m
−
1
) in the cell and the measured resistance was
800
o
hm
s
at
2
5
∘
C
. The constant will be
2593
221
WBJEE
WBJEE 2013
Electrochemistry
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A
1.02
c
m
−
1
6%
B
0.102
c
m
−
1
3%
C
1.00
c
m
−
1
90%
D
0.5
c
m
−
1
1%
Solution:
Given,
κ
=
1.25
×
1
0
−
3
S
c
m
−
1
ρ
=
K
1
=
1.25
×
1
0
−
3
1
S
−
1
c
m
From
R
=
ρ
A
I
800
=
1.25
×
1
0
−
3
1
×
A
1
(where,
A
l
=
cell constant)
∴
A
1
=
800
×
1.25
×
1
0
−
3
=
1
c
m
−
1