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Q. A conductivity cell has been calibrated with a $0.01 \,M \,1 : 1$ electrolyte solution (specific conductance, $k=1.25 \times 10^{-3}\, S\, cm^{-1}$) in the cell and the measured resistance was $800\, ohms$ at $25^{\circ}C$. The constant will be

WBJEEWBJEE 2013Electrochemistry

Solution:

Given, $ \kappa=1.25 \times 10^{-3} S cm ^{-1} $
$\rho =\frac{1}{ K }=\frac{1}{1.25 \times 10^{-3}} S ^{-1} \,cm$
From $ R=\rho \frac{I}{A}$
$800=\frac{1}{1.25 \times 10^{-3}} \times \frac{1}{A}$
(where, $\frac{l}{A}=$ cell constant)
$\therefore \frac{1}{A}=800 \times 1.25 \times 10^{-3}$
$=1 \,cm ^{-1} $