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Q. Will the dissociation of $ PC{{l}_{5}} $ in the reaction $ PC{{l}_{5}}(g)PC{{l}_{3}}(g)+C{{l}_{2}}(g);\Delta H=+2.22 $ Kcal be favoured by

AMUAMU 1996

Solution:

: As the reaction is endothermic and accompanied by an increase in volume, according to Le Chateliers principle favourable conditions for dissociation of $ PC{{l}_{5}} $ is increase in temperature and decrease in pressure.